Two-dimensional zeolites in catalysis: current status and perspectives

0462057 - ÚFCH JH 2017 RIV GB eng J - Journal Article
Opanasenko, Maksym - Roth, Wieslaw Jerzy - Čejka, Jiří
Two-dimensional zeolites in catalysis: current status and perspectives.
Catalysis Science &Technology. Roč. 6, č. 8 (2016), s. 2467-2484. ISSN 2044-4753. E-ISSN 2044-4761
R&D Projects: GA ČR GP13-17593P; GA ČR(CZ) GAP106/12/0189
Institutional support: RVO:61388955
Keywords : mesoporous molecular sieves * catalysis * acylation reactions
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 5.773, year: 2016

Two-dimensional zeolites have been studied and developed as diverse and fundamentally new forms of 3D framework structures. They can produce structures such as pillared, delaminated, interlamellar expanded and others, offering improved access to active sites and enhanced diffusion of reactants and products. This has been useful in catalysis showing particular benefits for reactions of larger reactants. Primary layered zeolite forms have been obtained by direct synthesis and also by degradation of existing frameworks with built-in weaknesses. Additional forms are obtained by post-synthesis modifications. This contribution presents an overview of results from catalytic testing of various 2D zeolites especially in comparison to their conventional 3D counterparts.

Permanent Link: http://hdl.handle.net/11104/0261599