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Nonaqueous capillary electrophoresis and quantum chemical calculations applied to investigation of acid-base and electromigration properties of azahelicenes
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SYSNO ASEP 0555579 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Nonaqueous capillary electrophoresis and quantum chemical calculations applied to investigation of acid-base and electromigration properties of azahelicenes Author(s) Šolínová, Veronika (UOCHB-X) RID, ORCID
Štěpánová, Sille (UOCHB-X) ORCID
Jančařík, Andrej (UOCHB-X) ORCID, RID
Klívar, Jiří (UOCHB-X) RID, ORCID
Šámal, Michal (UOCHB-X) RID, ORCID
Stará, Irena G. (UOCHB-X) RID, ORCID
Vacek Chocholoušová, Jana (UOCHB-X) RID, ORCID
Vacek, Jaroslav (UOCHB-X) RID, ORCID
Starý, Ivo (UOCHB-X) RID, ORCID
Kašička, Václav (UOCHB-X) RID, ORCIDSource Title Electrophoresis. - : Wiley - ISSN 0173-0835
Roč. 43, 5/6 (2022), s. 696-707Number of pages 12 s. Language eng - English Country DE - Germany Keywords acidity constant ; azahelicenes ; density functional theory ; ionization constant ; ionic mobility OECD category Organic chemistry R&D Projects GA20-03899S GA ČR - Czech Science Foundation (CSF) GA20-23566S GA ČR - Czech Science Foundation (CSF) Method of publishing Limited access Institutional support UOCHB-X - RVO:61388963 UT WOS 000736059500001 EID SCOPUS 85122130404 DOI 10.1002/elps.202100331 Annotation Nonaqueous capillary electrophoresis (NACE) using methanol (MeOH) as a solvent of the BGEs and quantum mechanical density functional theory (DFT) have been applied to determine the thermodynamic acidity (ionization) constants (pKa) of mono- and diaza[5]helicenes, mono- and diaza[6]helicenes, and their dibenzo derivatives in MeOH and water. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2023 Electronic address https://doi.org/10.1002/elps.202100331
Number of the records: 1