Number of the records: 1
Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines
- 1.
SYSNO ASEP 0506837 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Experimental and Theoretical Perspectives of the Noyori-Ikariya Asymmetric Transfer Hydrogenation of Imines Author(s) Václavík, J. (CZ)
Šot, P. (CZ)
Pecháček, J. (CZ)
Vilhanová, B. (CZ)
Matuška, O. (CZ)
Kuzma, Marek (MBU-M) ORCID, RID
Kačer, P. (CZ)Source Title Molecules. - : MDPI
Roč. 19, č. 6 (2014), s. 6987-7007Number of pages 21 s. Language eng - English Country CH - Switzerland Keywords ruthenium ; asymmetric hydrogenation ; imine Subject RIV EE - Microbiology, Virology OECD category Microbiology R&D Projects GAP106/12/1276 GA ČR - Czech Science Foundation (CSF) LO1509 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Research Infrastructure CESNET - 90005 - CESNET - zájmové sdružení právnických osob Method of publishing Open access Institutional support MBU-M - RVO:61388971 UT WOS 000338586700006 EID SCOPUS 84903288892 DOI 10.3390/molecules19066987 Annotation The asymmetric transfer hydrogenation (ATH) of imines catalyzed by the Noyori-Ikariya [RuCl(eta(6)-arene)(N-arylsulfonyl-DPEN)] (DPEN = 1,2-diphenylethylene-1,2- diamine) half-sandwich complexes is a research topic that is still being intensively developed. This article focuses on selected aspects of this catalytic system. First, a great deal of attention is devoted to the N-arylsulfonyl moiety of the catalysts in terms of its interaction with protonated imines (substrates) and amines (components of the hydrogen-donor mixture). The second part is oriented toward the role of the eta(6)-coordinated arene. The final part concerns the imine substrate structural modifications and their importance in connection with ATH. Throughout the text, the summary of known findings is complemented with newly-presented ones, which have been approached both experimentally and computationally. Workplace Institute of Microbiology Contact Eliška Spurná, eliska.spurna@biomed.cas.cz, Tel.: 241 062 231 Year of Publishing 2020 Electronic address https://www.mdpi.com/1420-3049/19/6/6987
Number of the records: 1