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Study of Asymmetric Stereoselective Hydrogenation in Presence of Ionic Liquid in Microfluidic Chip Reactor.
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SYSNO ASEP 0475758 Document Type C - Proceedings Paper (int. conf.) R&D Document Type The record was not marked in the RIV Title Study of Asymmetric Stereoselective Hydrogenation in Presence of Ionic Liquid in Microfluidic Chip Reactor. Author(s) Vychodilová, Hana (UCHP-M) RID, SAI
Stavárek, Petr (UCHP-M) RID, ORCID, SAI
Hejda, Stanislav (UCHP-M) RID, ORCID, SAI
Pěnkavová, Věra (UCHP-M) RID, ORCID, SAI
Bendová, Magdalena (UCHP-M) RID, ORCID, SAI
Vlček, Dalibor (UCHP-M) SAI
Klusoň, Petr (UCHP-M) RID, ORCID, SAISource Title Proceedings. - Bratislava : Slovak Society of Chemical Engineering, 2017 / Blahušiak M. ; Mihal M. - ISBN 978-80-89597-58-1 Pages s. 739 Number of pages 1 s. Publication form Medium - C Action International Conference of SSCHE /44./ Event date 22.05.2017 - 26.05.2017 VEvent location Demänovská dolina Country SK - Slovakia Event type EUR Language eng - English Country SK - Slovakia Keywords microfluidic chip reactor ; stereoselective hydrogenation ; ionic liquid Subject RIV CI - Industrial Chemistry, Chemical Engineering OECD category Chemical process engineering R&D Projects GA15-04790S GA ČR - Czech Science Foundation (CSF) Institutional support UCHP-M - RVO:67985858 Annotation In recent years, there have been several successful attempts of microreactor application to production of specialty chemicals [1,2] mainly for pharma and other related industry fields. In this study, we focused on the application of microfluidic chip reactor to the stereoselective hydrogenation of methylacetoacetate (MAA) to isomeric (R)-(+) or (S)-(-)-methyl-3-hydroxybutanoates over a chiral ([RuCl((R)-BINAP)(p-cymene)]Cl) complex [3] immobilized in the mixed [N8222][Tf2N]/methanol/water solvent phase, and performed inside of a microfluidic chip reactor. A presence of ionic liquid (quarternary ammonium salts) allows for an easy separation of this catalyst via its pseudo-immobilization. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2018
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