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Nucleated crystallization of isotactic polypropylene in multilayered sandwich nanocomposites with gold particles

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    SYSNO ASEP0377315
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleNucleated crystallization of isotactic polypropylene in multilayered sandwich nanocomposites with gold particles
    Author(s) Šlouf, Miroslav (UMCH-V) RID, ORCID
    Sikora, Antonín (UMCH-V) RID
    Pavlova, Ewa (UMCH-V) RID
    Vlková, Helena (UMCH-V)
    Baldrian, Josef (UMCH-V)
    Baše, Tomáš (UACH-T) RID, SAI, ORCID
    Piorkowska, E. (PL)
    Source TitleJournal of Applied Polymer Science. - : Wiley - ISSN 0021-8995
    Roč. 125, č. 6 (2012), s. 4338-4346
    Number of pages9 s.
    ActionInternational Conference on Polymer Behavior /4./
    Event date19.09.2010-23.09.2010
    VEvent locationLodz
    CountryPL - Poland
    Event typeWRD
    Languageeng - English
    CountryUS - United States
    Keywordsisotactic poly(propylene) ; nucleated crystallization ; gold nanoparticles
    Subject RIVEB - Genetics ; Molecular Biology
    Subject RIV - cooperationInstitute of Inorganic Chemistry - Physical ; Theoretical Chemistry
    R&D ProjectsGAP205/10/0348 GA ČR - Czech Science Foundation (CSF)
    KAN200520704 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40500505 - UMCH-V (2005-2011)
    AV0Z40320502 - UACH-T (2005-2011)
    UT WOS000304748300021
    DOI10.1002/app.36589
    AnnotationNucleation of isotactic polypropylene (PP) crystallization by gold particles with various sizes and shapes was studied. The morphology of gold particles ranged from microcrystals with well-developed crystal facets (AuMC) to vacuum-sputtered 5 nm gold nanoparticles (AuNP), 30 nm gold nanoislands (AuNI), and compact gold nanolayer (AuNL). The nucleated crystallization was studied by means of the improved sandwich method, which consisted in the controlled deposition of a homogeneous nucleant layer between ~ 100 μm PP films, followed by the careful thermal treatment and the evaluation of the nucleation activity by three independent methods: polarized-light microscopy, two-dimensional wide-angle X-ray scattering, and differential scanning calorimetry. It was demonstrated that the nucleating activity of gold strongly depended on its morphology.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2013
Number of the records: 1  

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