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Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy
- 1.0370610 - ÚFCH JH 2012 RIV US eng J - Journal Article
Ferus, Martin - Kubelík, Petr - Civiš, Svatopluk
Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy.
Journal of Physical Chemistry A. Roč. 115, č. 44 (2011), s. 12132-12141. ISSN 1089-5639. E-ISSN 1520-5215
R&D Projects: GA AV ČR IAA400400705; GA AV ČR IAAX00100903; GA ČR GAP208/10/2302
Institutional research plan: CEZ:AV0Z40400503
Keywords : FT-IR spectroscopy * high-power laser * induced dielectric-breakdown
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.946, year: 2011
High-resolution FT-IR spectroscopy was used for the analysis of the products of formamide dissociation using a high-energy Asterix laser. In the experiment, the detected products of the formamide LIDB dissociation were hydrogen cyanide, ammonia, carbon monoxide, carbon dioxide, nitrous oxide, hydroxylamine, and methanol. The molecular dynamics of the process was simulated with the use of a chemical model. The chemistry shared by formamide and the products of its dissociation is discussed with the respect to the formation of biomolecules.
Permanent Link: http://hdl.handle.net/11104/0006792
Number of the records: 1