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Catalytic properties of Ru-mordenite for NO reduction

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    SYSNO ASEP0097400
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleCatalytic properties of Ru-mordenite for NO reduction
    TitleKatalytické vlastnosti Ru-mordenitu pro redukci NO
    Author(s) Labhsetwar, NK. (JP)
    Minamino, H. (JP)
    Mukherjee, M. (IN)
    Mitsuhashi, T. (JP)
    Rayalu, S. (IN)
    Dhakad, M. (IN)
    Haneda, H. (JP)
    Šubrt, Jan (UACH-T) SAI, RID
    Devotta, S. (IN)
    Source TitleJournal of Molecular Catalysis A-Chemical. - : Elsevier - ISSN 1381-1169
    Roč. 261, č. 2 (2007), s. 213-217
    Number of pages5 s.
    Languageeng - English
    CountryNL - Netherlands
    KeywordsNO reduction ; catalyst ; Ru-zeolite
    Subject RIVCA - Inorganic Chemistry
    CEZAV0Z40320502 - UACH-T (2005-2011)
    AnnotationThe reduction of NO by CO over H and Na forms of Ru exchanged mordenite has been studied with ruthenium content of 0.2, 1 and 3 wt.percent. The catalysts were characterized with respect to X-ray diffraction, BET surface area, temperature programmed oxidation, and temperature programmed desorption of ammonia. These catalysts have been evaluated for their activity for NO-CO reaction using a steady state gas laboratory evaluation assembly. The catalysts show high activity for NO reduction and almost 100 percent conversion of NO to N-2 was observed below 400 degrees C. The activity was found to be a factor of ruthenium content, however, Ru-mordenite in Na form was observed to be relatively more active than Ru-mordenite in H form, probably due to the electron donation from sodium to ruthenium sites.
    WorkplaceInstitute of Inorganic Chemistry
    ContactJana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931
    Year of Publishing2008
Number of the records: 1  

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