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Structurally rigidified cobalt bis(dicarbollide) derivatives, a chiral platform for labelling of biomolecules and new materials
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SYSNO ASEP 0554162 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Structurally rigidified cobalt bis(dicarbollide) derivatives, a chiral platform for labelling of biomolecules and new materials Author(s) El Anwar, Suzan (UACH-T) SAI, ORCID, RID
Pazderová, Lucia (UACH-T) ORCID, SAI, RID
Bavol, Dmytro (UACH-T) SAI, RID, ORCID
Bakardjiev, Mario (UACH-T) SAI, RID
Růžičková, Z. (CZ)
Horáček, O. (CZ)
Fojt, Lukáš (BFU-R) RID, ORCID
Kučera, R. (CZ)
Grüner, Bohumír (UACH-T) RID, SAI, ORCIDNumber of authors 9 Source Title Chemical Communications. - : Royal Society of Chemistry - ISSN 1359-7345
Roč. 58, č. 15 (2022), s. 2572-2575Number of pages 4 s. Language eng - English Country GB - United Kingdom Keywords cosan Subject RIV CA - Inorganic Chemistry OECD category Inorganic and nuclear chemistry Subject RIV - cooperation Institute of Biophysics - Biochemistry R&D Projects GA19-04630S GA ČR - Czech Science Foundation (CSF) GA21-14409S GA ČR - Czech Science Foundation (CSF) Method of publishing Limited access Institutional support UACH-T - RVO:61388980 ; BFU-R - RVO:68081707 UT WOS 000750611500001 EID SCOPUS 85124805605 DOI 10.1039/d1cc06979a Annotation We report the difunctional modification of an anionic cobalta bis(dicarbollide)(1(-)) cluster with a B(8,8')-oxygen bridging unit that provides structural rigidity and an organic alkylazide substituent(s) on the carbon atoms of the metallacarborane cage. These ions present a good binding motif for incorporation into organic molecules using Huisgen-Sharpless (2+3) cycloaddition reactions. In addition, the compounds are chiral, as verified by separation of enantiomers using HPLC on chiral stationary phases (CSPs) and provide a high electrochemical peak in the window located outside of typical signals of biomolecules. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2022 Electronic address https://doi.org/10.1039/D1CC06979A
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