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Cumulene-like bridged indeno[1,2-b] fluorene π-conjugated polymers synthesized on metal surfaces
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SYSNO ASEP 0550863 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Cumulene-like bridged indeno[1,2-b] fluorene π-conjugated polymers synthesized on metal surfaces Author(s) Martín-Fuentes, C. (ES)
Urgel, J. I. (ES)
Edalatmanesh, Shayan (FZU-D) ORCID
Rodríguez-Sánchez, E. (ES)
Santos, J. (ES)
Mutombo, Pingo (FZU-D) RID, ORCID
Biswas, K. (ES)
Lauwaet, K. (ES)
Gallego, J. M. (ES)
Miranda, R. (ES)
Jelínek, Pavel (FZU-D) RID, ORCID
Martín, N. (ES)
Écija, D. (ES)Number of authors 13 Source Title Chemical Communications. - : Royal Society of Chemistry - ISSN 1359-7345
Roč. 57, č. 61 (2021), s. 7545-7548Number of pages 4 s. Language eng - English Country GB - United Kingdom Keywords on-surface synthesis ; polymers ; SPM ; DFT Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects GX20-13692X GA ČR - Czech Science Foundation (CSF) Method of publishing Limited access Institutional support FZU-D - RVO:68378271 UT WOS 000671616000001 EID SCOPUS 85111554478 DOI 10.1039/d1cc02058g Annotation Among the plethora of polycyclic structures that have emerged in recent years, indenofluorenes comprise a unique class of com pounds due to their potential in organic electronic systems such as OLEDs, OFETs, and OPVCs. However, the synthesis of fully conjugated indenofluorenes without bulky groups on the apical carbons under standard chemistry conditions is not easily acces sible. In this regard, on-surface synthesis has appeared as a newly developing field of research, which exploits the use of well-defined solid surfaces as confinement templates to initiate and develop chemical reactions. Here, we demonstrate the successful fabrica tion of indeno[1,2-b]fluorene p-conjugated polymers linked via cumulene-like connections on well-defined metallic surfaces under ultra-high vacuum conditions.
Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2022 Electronic address https://doi.org/10.1039/d1cc02058g
Number of the records: 1