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Proton-conducting polymer electrolytes based on methacrylates

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    0310764 - ÚACH 2009 RIV GB eng J - Journal Article
    Reiter, Jakub - Velická, Jana - Míka, M.
    Proton-conducting polymer electrolytes based on methacrylates.
    [Protonově vodivé polymerní elektrolyty na bázi methakrylátů.]
    Electrochimica acta. Roč. 53, č. 26 (2008), s. 7769-7774. ISSN 0013-4686. E-ISSN 1873-3859
    R&D Projects: GA ČR GA106/04/1279; GA AV ČR KJB400320701; GA MŠMT LC523; GA ČR(CZ) GA104/06/1471
    Institutional research plan: CEZ:AV0Z40320502
    Keywords : polymer electrolyte * proton conductivity * phosporic acid
    Subject RIV: CA - Inorganic Chemistry
    Impact factor: 3.078, year: 2008

    Anhydrous, proton conducting polymer electrolytes with phosphoric acid were prepared by direct, radical polymerization of methacrylates of different polarity, were studied using impedance, voltammetrical and thermogravimetric methods. Membranes of long-therm stability exhibit reasonable electrochemical stability and ionic conductivity especialy at elevated temperatures. they are thermally stable up to 110-130 degrees C.

    Byly připraveny bezvodé, protonově vodivé electrolyty s kyselinou fosforečnou a methakryláty s různou polaritou. Vzorky byly electrochemicky a termogravimetricky studovány a vykazují přijatelnou electrochemickou stabilitu a iontovou vodivost, především při vyšších teplotách. Jsou dlouhodobě stabilní a jsou odolné do teplot 110-130 stupňů C.
    Permanent Link: http://hdl.handle.net/11104/0162537

     
     
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