0566054 - ÚFCH JH 2024 RIV CH eng J - Journal Article
Zukalová, Markéta - Vinarčíková, Monika - Pitňa Lásková, Barbora - Kavan, Ladislav
TiO2 top layer improving the performance of sulfur/carbon composite cathode in Li-sulfur cells.
Materials Chemistry and Physics. Roč. 296, FEB 2023 (2023), č. článku 127246. ISSN 0254-0584. E-ISSN 1879-3312
R&D Projects: GA ČR(CZ) GA20-03564S
Institutional support: RVO:61388955
Keywords : battery * porous carbon * cyclic voltammetry * TiO2 * Li-sulfur
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Impact factor: 4.3, year: 2023 ; AIS: 0.584, rok: 2023
Method of publishing: Limited access
DOI: https://doi.org/10.1016/j.matchemphys.2022.127246

Facile preparation of the TiO2 top layer on the sulfur/carbon cathode in a Li-sulfur battery is presented. The layer significantly improves the initial charge capacity of composite cathodes. To demonstrate the versatility of the TiO2 top layer, its effect is evaluated on the sulfur composite cathodes with three kinds of carbonaceous additives. The electrochemical performance of these sulfur composite cathodes in the Li-sulfur battery is studied by cyclic voltammetry, galvanostatic chronopotentiometry, and electrochemical impedance spectroscopy. The sulfur/composite cathode with TOB carbon provides the highest charge capacity of 816 mAh g−1 from cyclic voltammetry, however, due to its structural disorder, exhibits the most pronounced capacity fade during galvanostatic cycling at 0.1C rate. The graphene nanoplatelets/sulfur composite cathode provides a charging capacity of 739 mAh g−1 in cyclic voltammetry and excellent cycling stability over 100 cycles of galvanostatic charging/discharging. A TiO2 top layer on the cathode and a TiO2-modified separator increase substantially the initial charge capacities of sulfur composite cathodes with all three kinds of carbon. The voltammetric charge capacities are 1427 mAh g−1, 1349 mAh g−1, and 952 mAh g−1 for TOB carbon, graphene nanoplatelets, and Penta carbon, respectively. This represents the relative enhancement by 75%, 83%, and 44%, respectively, as referenced to the cells with titania-free materials. Galvanostatic chronopotentiometry confirms the beneficial effect of inorganic additive on the charge capacity of Penta carbon and graphene nanoplatelets, however, the long-term cycling stability of the composite electrode is determined exclusively by the carbonaceous additive.
Permanent Link: https://hdl.handle.net/11104/0337494