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Tl.sub.0.6./sub.Mo.sub.3./sub.S.sub.5./sub., an original large tunnel-like molybdenum sulfide with Mo zigzag chains and disordered Tl cations
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SYSNO ASEP 0546393 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Tl0.6Mo3S5, an original large tunnel-like molybdenum sulfide with Mo zigzag chains and disordered Tl cations Author(s) Gougeon, P. (FR)
Gall, Ph. (FR)
Migot, S. (FR)
Ghanbaja, J. (FR)
Hervieu, M. (FR)
Levinský, Petr (FZU-D) RID, ORCID
Hejtmánek, Jiří (FZU-D) RID, ORCID
Dauscher, A. (FR)
Malaman, B. (FR)
Lenoir, B. (FR)
Candolfi, C. (FR)Number of authors 11 Source Title Materials Advances. - : Royal Society of Chemistry
Roč. 2, č. 18 (2021), s. 6020-6030Number of pages 11 s. Language eng - English Country GB - United Kingdom Keywords thermoelectric properties ; filled Mo-S cluster framework ; disordered compounds Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects GA18-12761S GA ČR - Czech Science Foundation (CSF) LM2018096 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Method of publishing Open access Institutional support FZU-D - RVO:68378271 UT WOS 000688154600001 EID SCOPUS 85115634498 DOI 10.1039/D1MA00568E Annotation We report on the crystal structure and physical properties of Tl0.6Mo3S5, which belongs to a novel family of materials with large tunnels, reminiscent of those observed in the romanechite structure type. Tl cations are partially filling these tunnels delimited by the Mo–S cluster framework in which the Mo atoms form infinite zigzag chains. Single-crystal X-ray diffraction data indicate that this compound crystallizes in the monoclinic, non-centrosymmetric space group P21 (no. 4, a = 9.344(2) Å, b = 3.234(2) Å, c = 11.669(2) Å and β = 113.09(2)° at 293 K). Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2022 Electronic address http://hdl.handle.net/11104/0323213
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