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Crystal structures of η''-Cu.sub.3+x./sub.Si and η'''-Cu.sub.3+x./sub.Si

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    0482895 - FZÚ 2018 RIV GB eng J - Journal Article
    Correa, Cinthia Antunes - Pérez, O. - Kopeček, Jaromír - Brázda, Petr - Klementová, Mariana - Palatinus, Lukáš
    Crystal structures of η''-Cu3+xSi and η'''-Cu3+xSi.
    Acta Crystallographica Section B-Structural Science Crystal Engineering and Materials. Roč. 73, č. 4 (2017), s. 767-774. E-ISSN 2052-5206
    R&D Projects: GA ČR GC15-08842J
    Institutional support: RVO:68378271
    Keywords : copper silicide * incommensurately modulated structure * superstructure
    OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
    Impact factor: 6.467, year: 2017

    The binary phase diagram of Cu–Si is unexpectedly complex in the vicinity of Cu3+xSi . The low-temperature region contains three closely related incommensurately modulated phases. The structures could be solved in superspace, but no superspace structure model could be constructed due to the complexity of the modulation functions. Therefore, the structures were described in a supercell approximation.

    Permanent Link: http://hdl.handle.net/11104/0278282

     
     
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