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The reaction of (Sp)-2-(diphenylphosphino)ferrocenecarboxylic acid with carbodiimide reagents: Characterisation of the acid anhydride and urea products

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    0313467 - ÚOCHB 2009 RIV CH eng J - Journal Article
    Lamač, M. - Cvačka, Josef - Štěpnička, P.
    The reaction of (Sp)-2-(diphenylphosphino)ferrocenecarboxylic acid with carbodiimide reagents: Characterisation of the acid anhydride and urea products.
    [Reakce (Sp)-2-difenylfosfino)ferrocenkarboxylové kyseliny s karbodiimidovými činidly: Charakterizace anhydridu a močovinových produktů.]
    Journal of Organometallic Chemistry. Roč. 693, 21/22 (2008), s. 3430-3434. ISSN 0022-328X. E-ISSN 1872-8561
    Grant - others:GA MŠk(CZ) LC06070
    Program: LC
    Institutional research plan: CEZ:AV0Z40550506
    Keywords : ferrocene * urea derivatives * carbodiimide coupling
    Subject RIV: CC - Organic Chemistry
    Impact factor: 1.866, year: 2008

    Interaction of (Sp)-2-(diphenylphosphino)ferrocenecarboxylic acid [(Sp)-1] with N,N0-dicyclohexylcarbodiimide and N-ethyl-N0-[3-(dimethylamino)propyl]carbodiimide have been investigated in order to study the reacting system itself and to characterise side-products typically arising during the diimide-promoted condensation of acid (Sp)-1 with nucleophiles.

    Byla studována reakce kyseliny (Sp)-2-(difenylfosfino)ferrocenkarboxylové [(Sp)-1] s N,N0-dicyklohexylkarbodiimidem and N-ethyl-N0-[3-(dimethylamino)propyl]karbodiimidem. Byly charakterizovány vedlejší produkty, které vznikají během kondenzace kyseliny (Sp)-1 s nukleofily.
    Permanent Link: http://hdl.handle.net/11104/0164277

     
     
Number of the records: 1  

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