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Surface Inclusion of Unidirectional Molecular Motors in Hexagonal Tris(o-phenylene)cyclotriphosphazene
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SYSNO ASEP 0478106 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Surface Inclusion of Unidirectional Molecular Motors in Hexagonal Tris(o-phenylene)cyclotriphosphazene Author(s) Kaleta, Jiří (UOCHB-X) RID, ORCID
Chen, J. (NL)
Bastien, Guillaume (UOCHB-X) ORCID
Dračínský, Martin (UOCHB-X) RID, ORCID
Mašát, Milan (UOCHB-X) RID, ORCID
Rogers, C. T. (US)
Feringa, B. L. (NL)
Michl, Josef (UOCHB-X) RID, ORCIDSource Title Journal of the American Chemical Society. - : American Chemical Society - ISSN 0002-7863
Roč. 139, č. 30 (2017), s. 10486-10498Number of pages 13 s. Language eng - English Country US - United States Keywords solid state ; structural modification ; aromatic nanochannels Subject RIV CC - Organic Chemistry OECD category Organic chemistry R&D Projects GA15-11223S GA ČR - Czech Science Foundation (CSF) Institutional support UOCHB-X - RVO:61388963 UT WOS 000407089500043 EID SCOPUS 85026804469 DOI 10.1021/jacs.7b05404 Annotation A new unidirectional light-driven molecular motor suitable for host guest surface inclusion complexes with tris(o-phenylene)cyclotriphosphazene (TPP) was synthesized. The motor molecules formed regular two-dimensional trigonal arrays covering the large facets of disc-shaped TPP nanocrystals. Photochemical and thermal isomerization studies demonstrated that the light driven rotation of the anchored motors is similar to that observed in solution and is not compromised neither by either the surface confinement or the density of surface coverage (.50 vs 100%). Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2018
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