Synthesis of the cerium doped Gd.sub.3./sub.Al.sub.3./sub.Ga.sub.2./sub.O.sub.12./sub.-based glass nanoceramics: Luminescence and optical absorption properties

0572396 - FZÚ 2024 RIV GB eng J - Journal Article
Buryi, Maksym - Tratsiak, Y. - Trusova, E. - Babin, Vladimir - Páterek, Juraj - Kučerková, Romana - Remeš, Zdeněk - Hájek, František - Landová, Lucie - Drahokoupil, Jan - Chertopalov, Sergii
Synthesis of the cerium doped Gd₃Al₃Ga₂O₁₂-based glass nanoceramics: Luminescence and optical absorption properties.
Radiation Measurements. Roč. 163, April (2023), č. článku 106932. ISSN 1350-4487. E-ISSN 1879-0925
Grant - others:AV ČR(CZ) NASB-20-03
Program: Bilaterální spolupráce
Institutional support: RVO:68378271
Keywords : Gd₃Al₃Ga₂O₁₂ * glass ceramics * Ce³⁺ doping * luminescence * decay kinetics
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 2, year: 2022
Method of publishing: Limited access
https://doi.org/10.1016/j.radmeas.2023.106932

Cerium doped gadolinium gallium aluminum garnet (Gd3Al3Ga2O12, GAGG) was synthesized in the glass ceramics form by the crystallization from Gd2O3–Al2O3–Ga2O3–SiO2–CeO2 glass in the following weight proportion: 101 : 26: 47 : 25: 1. The spatial distribution and incorporation of Ce into the GAGG ceramic grains as well as the luminescence and scintillation performance are studied carrying out correlated experiments of photo-, radio- and cathodoluminescence including decay kinetics as well as energy dispersive X-ray spectroscopy combined with scanning electron microscopy. Optical absorption features were investigated using photothermal deflection spectroscopy. Cerium stays within the material mostly in the Ce3+ charge state. Its distribution in the bulk of the sample exhibits irregular trend indicating the tendency to coalesce in the middle.
Permanent Link: https://hdl.handle.net/11104/0346911