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Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications
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SYSNO ASEP 0569146 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications Author(s) Kirakci, Kaplan (UACH-T) SAI, RID, ORCID
Shestopalov, M.A. (RU)
Lang, Kamil (UACH-T) SAI, RID, ORCIDNumber of authors 3 Article number 215048 Source Title Coordination Chemistry Reviews. - : Elsevier - ISSN 0010-8545
Roč. 481, APR (2023)Number of pages 30 s. Language eng - English Country NL - Netherlands Keywords hexanuclear molybdenum clusters ; core-containing clusters ; biological applications Subject RIV CA - Inorganic Chemistry OECD category Inorganic and nuclear chemistry R&D Projects GC21-16084J GA ČR - Czech Science Foundation (CSF) GA21-11688S GA ČR - Czech Science Foundation (CSF) Method of publishing Limited access Institutional support UACH-T - RVO:61388980 UT WOS 000944220900001 EID SCOPUS 85147865538 DOI 10.1016/j.ccr.2023.215048 Annotation The luminescent octahedral molybdenum, tungsten, and rhenium cluster complexes have attracted a broad interest in the past decades for the design of photofunctional materials. These complexes, with the general formula [{M6Li8}La6]n, display red phosphorescence with high quantum yields, quenching of their emission by oxygen, and robust production of singlet oxygen, O2(1Δg). In addition, the wide range of inner (Li) and apical (La) ligands allows for a fine tuning of their physico-chemical, photophysical, and biological properties and for additional functionalization with regards to targeted applications. In this review, we summarize the recent developments towards the use of these complexes for biological applications such as photodynamic therapy, computed tomography, or photoinactivation of bacteria. The synthetic methods and properties of these complexes are presented and we encompass the different approaches towards photo-related biological applications through standalone use of these complexes or by their incorporation into (nano)materials. We identify the key parameters and the challenges for successful biological application of this class of transition metal cluster complexes. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2024 Electronic address https://doi.org/10.1016/j.ccr.2023.215048
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