0552055 - ÚOCHB 2023 RIV US eng J - Journal Article
Zajac, G. - Bouř, Petr
Measurement and Theory of Resonance Raman Optical Activity for Gases, Liquids, and Aggregates. What It Tells about Molecules.
Journal of Physical Chemistry B. Roč. 126, č. 2 (2022), s. 355-367. ISSN 1520-6106. E-ISSN 1520-5207
R&D Projects: GA MŠMT(CZ) EF16_019/0000729; GA ČR(CZ) GA20-10144S
Institutional support: RVO:61388963
Keywords : optical materials * chiroptical spectroscopy * resonance
OECD category: Physical chemistry
Impact factor: 3.3, year: 2022
Method of publishing: Limited access
https://doi.org/10.1021/acs.jpcb.1c08370

Resonance Raman Optical Activity (RROA) appeared as a natural extension of the nonresonance branch. It combines the structural sensitivity of chiroptical spectroscopy with the signal enhancement coming from the resonance of molecular electronic transitions with the excitation laser light. However, the idea has been hampered by many technical and theoretical problems that are being clarified only in recent years. We provide the theoretical basis and several examples documenting the problems, achievements, and potential of RROA, in particular in biomolecular studies.
Permanent Link: http://hdl.handle.net/11104/0327217