1D copper(I) coordination polymer [Cu.sub.2./sub.(μ-(2,4-Cl-ba).sub.2./sub.bn)(μ-I.sub.2./sub.).sub.n./sub.] with a flexible Schiff base ligand: synthesis, crystal structure, and thermal stability

0521557 - FZÚ 2020 RIV RU eng J - Journal Article
Khalaji, A.D. - Peyghoun, S.J. - Dušek, Michal - Eigner, Václav
1D copper(I) coordination polymer [Cu₂(μ-(2,4-Cl-ba)₂bn)(μ-I₂)_n] with a flexible Schiff base ligand: synthesis, crystal structure, and thermal stability.
Journal of Structural Chemistry. Roč. 60, č. 12 (2019), s. 1983-1988. ISSN 0022-4766. E-ISSN 1573-8779
R&D Projects: GA ČR(CZ) GA18-10438S; GA MŠMT(CZ) LO1603
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : 1D copper(I) coordination polymer * single crystal * triangle * thermogravimetry * crystal structure
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 0.745, year: 2019
Method of publishing: Limited access
https://doi.org/10.1134/s002247661912014x

In this paper, bis-monodentate Schiff base ligand (2,4-Cl-ba)2bn and its 1D copper(I) coordination polymer [Cu2(μ-(2,4-Cl-ba)2bn)(μ-I2)n] are synthesized and characterized by the elemental analysis (CHN), FT-IR and 1H NMR spectroscopy. Their crystal structure is determined from the single crystal X-ray diffraction analysis. The thermal behavior of the complex is studied using thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathway.

Permanent Link: http://hdl.handle.net/11104/0306153