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Influence of substituents in meso-aryl groups of iron l-oxo porphyrins\non their catalytic activity in the oxidation of cycloalkanes
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SYSNO ASEP 0466974 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Influence of substituents in meso-aryl groups of iron l-oxo porphyrins
on their catalytic activity in the oxidation of cycloalkanesAuthor(s) Tabor, Edyta (UFCH-W) RID, ORCID
Poltowicz, J. (PL)
Pamin, K. (PL)
Basag, S. (PL)
Kubiak, W. (PL)Source Title Polyhedron. - : Elsevier - ISSN 0277-5387
Roč. 119, NOV 2016 (2016), s. 342-349Number of pages 8 s. Language eng - English Country GB - United Kingdom Keywords iron porphyrins ; μ-Oxo porphyrins ; oxidation Subject RIV CF - Physical ; Theoretical Chemistry Institutional support UFCH-W - RVO:61388955 UT WOS 000389165400039 EID SCOPUS 84989284825 DOI https://doi.org/10.1016/j.poly.2016.08.048 Annotation The aim of this work was to study the effect of substituents on the catalytic activity of iron μ-oxo porphyrins in oxidation of cycloalkanes. Electron-donating or electron-withdrawing substituents were introduced in meso-aryl groups of iron μ-oxo porphyrins. An important part of the work was the characterization of the catalysts, in particular their redox properties. Catalytic performance and selectivity were evaluated using cyclopentane, cyclohexane, and cyclooctane as model compounds. It was shown that not only electron-withdrawing but also electron-donating substituents improved the catalytic performance of iron μ-oxo complexes. Moreover, catalytic activity of iron μ-oxo porphyrins with electron-withdrawing substituents correlated with the half-wave potential E1/2 while the catalytic activity of iron μ-oxo porphyrins with electron-donating substituents increased with the decrease of reduction potential ERED. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2017
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