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The pi Complex of the Hydronium Ion Frozen on the Pathway of Electrophilic Aromatic Substitution
- 1.0463786 - ÚACH 2017 RIV DE eng J - Journal Article
Růžičková, Z. - Holub, Josef - Melichar, Petr - Moncol, J. - Wann, D. A. - Fanfrlík, Jindřich - Růžička, A. - Hnyk, Drahomír
The pi Complex of the Hydronium Ion Frozen on the Pathway of Electrophilic Aromatic Substitution.
European Journal of Organic Chemistry. Roč. 2016, č. 26 (2016), s. 4473-4475. ISSN 1434-193X. E-ISSN 1099-0690
R&D Projects: GA ČR(CZ) GBP208/12/G016
Institutional support: RVO:61388980 ; RVO:61388963
Keywords : Anions * Pi complexes * Electrophilic substitution * Quantum mechanics * Structure elucidation
Subject RIV: CA - Inorganic Chemistry; CF - Physical ; Theoretical Chemistry (UOCHB-X)
Impact factor: 2.834, year: 2016
A very rare crystal was prepared consisting of a 2D aromatic (toluene) together with a weakly coordinating 3D aromatic (closo-1-CB11H12-) and a hydronium ion, and this crystal was analyzed by using X-ray diffraction and high-level quantum-mechanical calculations. The nature of the crystal arrangement made it possible to detect the frozen complex that would originate during protonation of toluene by the acidic hydronium ion.
Permanent Link: http://hdl.handle.net/11104/0262872
Number of the records: 1