Number of the records: 1
A new copper(II) Schiff base complex containing asymmetrical tetradentate N.sub.2./sub.O.sub.2./sub. Schiff base ligand: Synthesis, characterization, crystal structure and DFT study
- 1.
SYSNO ASEP 0448378 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title A new copper(II) Schiff base complex containing asymmetrical tetradentate N2O2 Schiff base ligand: Synthesis, characterization, crystal structure and DFT study Author(s) Grivani, G. (IR)
Baghan, S.H. (IR)
Vakili, M. (IR)
Khalaji, A.D. (IR)
Tahmasebi, V. (IR)
Eigner, Václav (FZU-D) RID, ORCID
Dušek, Michal (FZU-D) RID, ORCID, SAISource Title Journal of Molecular Structure. - : Elsevier - ISSN 0022-2860
Roč. 1082, Feb (2015), 91-96Number of pages 6 s. Language eng - English Country NL - Netherlands Keywords Schiff-base ; copper (II) ; complex ; single-crystal ; thermal decomposition ; DFT Subject RIV BM - Solid Matter Physics ; Magnetism R&D Projects GA14-03276S GA ČR - Czech Science Foundation (CSF) Institutional support FZU-D - RVO:68378271 UT WOS 000347591100011 EID SCOPUS 84911926108 DOI 10.1016/j.molstruc.2014.10.058 Annotation A new copper (II) Schiff base complex, CuL1, was prepared from the reaction of asymmetrical Schiff base ligand of L1 and Cu(OAC)2 (L1 = salicylidene imino-ethylimino-pentan-2-one). The Schiff base ligand, L1, and its copper (II) complex, CuL1, have been characterized by elemental analysis (CHN) and FT-IR and UV–vis spectroscopy. In addition, 1H NMR was employed for characterization of the ligand. Thermogrametric analysis of the CuL1 reveals its thermal stability and its decomposition pattern shows that it is finally decomposed to the copper oxide (CuO). The crystal structure of CuL1 was determined by the single crystal X-ray analysis. The CuL1 complex crystallizes in the monoclinic system, with space group P21/n and distorted square planar coordination around the metal ion. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2016
Number of the records: 1