Photo-patterning of non-fouling polymers and biomolecules on paper

0429251 - ÚMCH 2015 RIV DE eng J - Journal Article
Tischer, T. - Rodriguez-Emmenegger, Cesar - Trouillet, V. - Welle, A. - Schueler, V. - Mueller, J. O. - Goldmann, A. S. - Brynda, Eduard - Barner-Kowollik, C.
Photo-patterning of non-fouling polymers and biomolecules on paper.
Advanced Materials. Roč. 26, č. 24 (2014), s. 4087-4092. ISSN 0935-9648. E-ISSN 1521-4095
R&D Projects: GA ČR GAP205/12/1702; GA MŠMT(CZ) LH13178; GA MŠMT(CZ) ED1.1.00/02.0109
Institutional support: RVO:61389013
Keywords : bioactive paper * micropatterning * nitrile imine-mediated tetrazole-ene cycloaddition (NITEC)
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 17.493, year: 2014

Functional cellulose substrates with tetrazole moieties are generated to serve as universal platforms for the spatio-temporal immobilization of synthetic ultra-low fouling polymer brushes and protein species via a nitrile imine-mediated tetrazole-ene cycloaddition (NITEC)-based protocol. Poly(carboxybetaine acrylamide) brushes are grafted from initiators photo-patterned by NITEC utilizing single electron transfer living radical polymerization. Streptavidin is photo-immobilized with remarkable efficiency, opening the possibility to generate new materials for biomedical and biosensing applications.
Permanent Link: http://hdl.handle.net/11104/0235056