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Metal Mixed Oxides and Zeolites in Oxidation of Ethanol and Isopropanol
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SYSNO ASEP 0427926 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Metal Mixed Oxides and Zeolites in Oxidation of Ethanol and Isopropanol Author(s) Gaálová, Jana (UCHP-M) RID, SAI, ORCID
Jirátová, Květa (UCHP-M) RID, ORCID, SAI
Klempa, Jan (UCHP-M)
Šolcová, Olga (UCHP-M) RID, ORCID, SAI
Maupin, I. (FR)
Mijoin, J. (FR)
Magnoux, P. (FR)
Barbier Jr., J. (FR)Source Title Proceedings. - - : -, 2014 / Razeghi M. - ISBN 978-1-61804-223-1 Pages s. 113-120 Number of pages 8 s. Publication form Medium - C Action 2014 International Conference on Chemical Engineering and Materials Science (CEMS '14) Event date 15.03.2014-17.03.2014 VEvent location Venice Country IT - Italy Event type EUR Language eng - English Country IT - Italy Keywords ethanol ; isopropanol ; metal mixed oxide Subject RIV DK - Soil Contamination ; De-contamination incl. Pesticides R&D Projects FR-TI1/059 GA MPO - Ministry of Industry and Trade (MPO) Institutional support UCHP-M - RVO:67985858 Annotation The different kinds of catalysts – zeolite, (mixed) oxide – were tested and compared in catalytic oxidation of ethanol and isopropanol respectively. All catalysts proved remarkable aktivity in catalytic oxidation of selected model compounds. Even the less active catalyst, basic zeolite NaX, converted 50 % of ethanol as well as isopropanol at around 300 °C. The deepen comparison revealed that CeO2 and zeolite NaX-CeO2 is more suitable for oxidation of isopropanol while oxidation of ethanol is faster in a presence of the metal mixed oxides, Co4MnAl and NiMgMn. The additional contribution of the present article is a comparison of certain catalysts properties linked directly to the catalytic performance in the oxidation processes, such as oxygen storage capacity (OSC), surface properties, acidity/basicity and others. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2015 Electronic address http://www.europment.org/library/2014/venice/bypaper/BICHE/BICHE-20.pdf
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