Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.1.sup.3,8./sup.]undecane (TATU)

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SYSNO ASEP	0365631
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Synthesis and structural studies of a new class of quaternary ammonium salts, which are derivatives of cage adamanzane type aminal 1,3,6,8-tetraazatricyclo [4.3.1.1^3,8]undecane (TATU)
Author(s)	Rivera, A. (CO) Sadat-Bernal, J. (CO) Ríos-Motta, J. (CO) Dušek, Michal (FZU-D)_{RID, ORCID, SAI} Palatinus, Lukáš (FZU-D)_{RID, ORCID}
Source Title	Chemistry Central Journal - ISSN 1752-153X Roč. 5, č. 55 (2011), 55/1-55/8
Number of pages	8 s.
Language	eng - English
Country	GB - United Kingdom
Keywords	quaternary ammonium salts ; adamanzane ; X-ray diffraction
Subject RIV	BM - Solid Matter Physics ; Magnetism
CEZ	AV0Z10100521 - FZU-D (2005-2011)
UT WOS	000295921700001
DOI	10.1186/1752-153X-5-55
Annotation	Novel mono N-alkyl quaternary ammonium salts (3a-f) were prepared using the Menschutkin reaction. The structures of these new salts were established using various spectral and electrospray ionization mass spectrometry (ESI-MS) analyses. Compound (3b) was also analyzed using X-ray crystallography. It was noted that alkyl chain length did not significantly affect the reaction because all employed alkyl iodide electrophiles reacted in a similar fashion with the aminal 1.
Workplace	Institute of Physics
Contact	Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579
Year of Publishing	2012

Number of the records: 1