Number of the records: 1
Preparation, Crystal Structure and Spectroscopic Properties of Dimeric [Zn(2-bromobenzoato)(2)(phenazone)](2) and Monomeric [Zn(2-bromobenzoato)(2)(thiourea)(2)]center dot 2H(2)O
- 1.
SYSNO ASEP 0364607 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Preparation, Crystal Structure and Spectroscopic Properties of Dimeric [Zn(2-bromobenzoato)(2)(phenazone)](2) and Monomeric [Zn(2-bromobenzoato)(2)(thiourea)(2)]center dot 2H(2)O Author(s) Krajniková, A. (SK)
Gyepes, Robert (UFCH-W) RID, ORCID
Györyová, K. (SK)
Šubrt, Jan (UACH-T) SAI, RID
Imrich, J. (SK)Source Title Journal of Chemical Crystallography. - : Springer - ISSN 1074-1542
Roč. 41, č. 7 (2011), s. 1036-1043Number of pages 8 s. Language eng - English Country US - United States Keywords crystal structure ; phenazone ; spectroscopy Subject RIV CF - Physical ; Theoretical Chemistry CEZ AV0Z40400503 - UFCH-W (2005-2011) AV0Z40320502 - UACH-T (2005-2011) UT WOS 000292841400022 DOI 10.1007/s10870-011-0041-7 Annotation The binuclear zinc complex bis(2-bromobenzoato- O)-bis(mu(2)-2-bromobenzoato-O,O')-bis(phenazone-O) -dizinc(II) (I) and the mononuclear dihydrate bis(2-bromobenzoato- O)-bis(thiourea-S)-zinc(II) (II) have been synthesized and characterized by means of elemental analysis and spectroscopic methods (IR, (1)H and (13)C NMR, EDS). The solid state structures of both compounds were determined by single-crystal X-ray diffractometry. Compound [Zn(2-BrC(6)H(4)COO)(2)(phen)](2) (phen-phenazone) (I) crystallized as a dimeric compound with a triclinic lattice (space group P - 1), where both zinc atoms, inter-connected by two carboxylate groups, possess a distorted tetrahedral coordination environment. The crystallographic data of complex I: a = 9.9410(3) angstrom, b = 10.7309(3) angstrom, c = 12.9237(4) angstrom, alpha = 93.6004(17)degrees, beta = 92.5898(11)degrees, gamma = 116.2192(16)degrees, V = 1230.26(6) angstrom(3), Z = 1. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2012
Number of the records: 1