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Oxidatively Induced Concurrent Cationic and Radical Polymerization of Isobutylene in the Presence of LiCB(11)Me(12)
- 1.0361440 - ÚOCHB 2012 RIV US eng J - Journal Article
Volkis, V. - Douvris, C. - Michl, Josef
Oxidatively Induced Concurrent Cationic and Radical Polymerization of Isobutylene in the Presence of LiCB(11)Me(12).
Journal of the American Chemical Society. Roč. 133, č. 20 (2011), s. 7801-7809. ISSN 0002-7863. E-ISSN 1520-5126
Grant - others:NSF(US) CHE-0715374
Institutional research plan: CEZ:AV0Z40550506
Keywords : permethylated icosahedral anion CB11Me12 * concurrent cationic and radical polymerization of isobutylene
Subject RIV: CC - Organic Chemistry
Impact factor: 9.907, year: 2011
Concurrent cationic and radical polymerization of isobutylene in presence of LiCB11Me12 anion is described. Mechanistic explanation of polymerization is discused on the base of influnce of lithium salt of permethylated icosahedral anion CB11Me12-. A closer investigation confirmed that, in the presence of LiCB11Me12 in weakly coordinating solvents radical polymerization of isobutylene takes place.
Permanent Link: http://hdl.handle.net/11104/0198751
Number of the records: 1