Number of the records: 1
A rapid one-step mechanosynthesis and characterization of nanocrystalline CaFe2O4 with orthorhombic structure
- 1.
SYSNO ASEP 0357664 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title A rapid one-step mechanosynthesis and characterization of nanocrystalline CaFe2O4 with orthorhombic structure Author(s) Berchmans, L.J. (IN)
Myndyk, M. (DE)
da Silva, K.L. (BR)
Feldhoff, A. (DE)
Šubrt, Jan (UACH-T) SAI, RID
Heitjans, P. (DE)
Becker, K.D. (DE)
Sepelak, V. (DE)Source Title Journal of Alloys and Compounds. - : Elsevier - ISSN 0925-8388
Roč. 500, č. 1 (2010), s. 68-73Number of pages 6 s. Language eng - English Country NL - Netherlands Keywords nanostructured materials ; mechanochemical processing ; microstructure ; core-shell morphology ; Mossbauer spectroscopy Subject RIV CA - Inorganic Chemistry CEZ AV0Z40320502 - UACH-T (2005-2011) UT WOS 000279139400018 DOI 10.1016/j.jallcom.2010.03.199 Annotation CaFe2O4 nanopowders were prepared via single-step mechanochemical processing of two various mixtures of precursors: simple oxides (CaO and alpha-Fe2O3) and elemental metal and oxide powders (Ca and alpha-Fe2O3). The mechanically induced evolution of the CaO/alpha-Fe2O3 and Ca/alpha-Fe2O3 mixtures was followed by Fe-57 Mossbauer spectroscopy, XRD, and HR-TEM. The mechanosynthesis of CaFe2O4 proceeds very rapidly if starting from the metal/oxide system: after only 1 h of the mechanochemical treatment performed at room temperature, the synthesis of the complex oxide is almost completed. This is in a strong contrast to the conventional solid-state synthesis of CaFe2O4, which requires prolonged exposure (similar to 20 h) at considerably elevated temperatures (similar to 1400 K). Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2011
Number of the records: 1