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Synthesis and characterization of dicarboranylmethylammonium polyoxometalles
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SYSNO ASEP 0357040 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Synthesis and characterization of dicarboranylmethylammonium polyoxometalles Author(s) Macias, R. (ES)
Kennedy, J.D. (GB)
Bould, Jonathan (UACH-T) SAI, RID, ORCID
Thomton-Pett, M. (GB)Source Title Collection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765
Roč. 75, č. 11 (2010), s. 1075-1096Number of pages 22 s. Language eng - English Country CZ - Czech Republic Keywords carboranes ; polyoxometallates ; hybrid salts Subject RIV CA - Inorganic Chemistry CEZ AV0Z40320502 - UACH-T (2005-2011) UT WOS 000284230500002 DOI 10.1135/cccc2010056 Annotation Crystal structures reveal the presence of various small solvate molecules, together with an extensive network of hydrogen bonds between ammonium groups and oxygen atoms of the isopolyoxometallates. The isopropyl substituent in one of the carborane cations of the salts 6 and the ethyl substituent in one of the carborane cations of salts 8 may result from occluded isopropanol and ethanol in the starting salt 3 with alkylations of the primary ammonium group being assisted by isopolymolybdate anions. The presence of the pyridinium cation in 11 is believed to arise from contamination during work-up the reaction mixture. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2011
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