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Heterogenized Homogeneous Catalysts for Fine Chemicals Production
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SYSNO ASEP 0341534 Document Type M - Monograph Chapter R&D Document Type Monograph Chapter Title Chemoselective and Enantioselective Hydrogenations on Immobilized Complexes Author(s) Zsigmond, A. (HU)
Notheisz, F. (HU)
Klusoň, Petr (UCHP-M) RID, ORCID, SAI
Floriš, Tomáš (UCHP-M)Source Title Heterogenized Homogeneous Catalysts for Fine Chemicals Production, Catalysis by Metal Complexes, Vol. 34. - Dordrecht : Springer, 2010 / Barbaro P. ; Liguori F. - ISBN 978-90-481-3695-7 Pages s. 283-360 Number of pages 78 s. Number of copy 600 Number of pages 459 Language eng - English Country DE - Germany Keywords Ru-BINAP ; hydrogenation ; ionic liquids Subject RIV CC - Organic Chemistry CEZ AV0Z40720504 - UCHP-M (2005-2011) DOI 10,1007/978-90-481-3696-4 Annotation Homogeneous catalysts, which are mixed with the reactants at the molecular level, typically show the highest activity and selectivity as they offer chemically well-defined active sites and are not limited by heat and mass transport. However, an inherent disadvantage of the homogeneous catalysis is the need to separate the catalyst from a product after the reaction. Therefore, solid or immobilized homogeneous catalysts are preferred in industry. In this contribution we pay attention to chemoselectivity, regioselectivity and enantio¬selectivity in the synthesis of fine chemicals by means of hydrogenation reactions with immobilised homogeneous complexes. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2011
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