Selective Synthesis of Z-1,4-Disilyl-2-butenes

Number of the records: 1

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SYSNO ASEP	0332607
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Selective Synthesis of Z-1,4-Disilyl-2-butenes
Title	Selektivní příprava Z-1,4-Disilyl-2-butenů
Author(s)	Šabata, Stanislav (UCHP-M)_{RID, ORCID, SAI} Blechta, Vratislav (UCHP-M)_{RID, ORCID, SAI} Karban, Jindřich (UCHP-M)_{RID, ORCID, SAI} Pleska, A. (CZ) Včelák, Jaroslav (UCHP-M) Hetflejš, Jiří (UCHP-M)
Source Title	Polish Journal of Chemistry - ISSN 0137-5083 Roč. 83, č. 11 (2009), s. 1953-1958
Number of pages	6 s.
Language	eng - English
Country	PL - Poland
Keywords	Z-1,4-disilyl-2-butenes ; 1,4-dilithio-2-butene ; trialkylchlorosilanes
Subject RIV	CC - Organic Chemistry
R&D Projects	GA203/03/0617 GA ČR - Czech Science Foundation (CSF)
	GA203/03/1566 GA ČR - Czech Science Foundation (CSF)
CEZ	AV0Z40720504 - UCHP-M (2005-2011)
UT WOS	000271550800011
Annotation	Z-1,4-Disilyl-2-butenes, R3SiCH2CH=CHCH2SiR3 (R3 = Me3, Me2H, Me2(ClCH2), Me2Ph(CH2)3, Me(2-Bu)2 and Et3) have been pre pared in high yields by the re ac tion of 1,4-dilithio-2-butene with the corresponding trialkylchlorosilanes, us ing tert-butyl methyl ether as the solvent. The course of ananalogous reaction of dimethyldichlorosilane is briefly discussed.
Workplace	Institute of Chemical Process Fundamentals
Contact	Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
Year of Publishing	2010

Number of the records: 1