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Can Electrospray Mass Spectrometry Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods
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SYSNO ASEP 0329546 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Can Electrospray Mass Spectrometry Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods Author(s) Tsierkezos, Nikos (UOCHB-X)
Roithová, Jana (UOCHB-X)
Schröder, Detlef (UOCHB-X)
Ončák, Milan (UFCH-W) ORCID, RID
Slavíček, Petr (UFCH-W) RIDNumber of authors 5 Source Title Inorganic Chemistry. - : American Chemical Society - ISSN 0020-1669
Roč. 48, č. 13 (2009), s. 6287-6296Number of pages 10 s. Language eng - English Country US - United States Keywords collision-induced dissociation ; electrodpray ionization ; ion association ; mass spectrometry Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA203/08/1487 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000267507400083 DOI 10.1021/ic900575r Annotation Electrospray ionization of uranyl nitrate dissolved in water leads to the contact-ion pairs [UO2(OH)]+ and [UO2(NO3)]+ solvated by up to four water molecules. The dependences of the ion intensities from the concentrations lead to a quantitative correlation between the gas-phase and solution-phase data. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2010
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