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Hydrothermal synthesis, structural and physico-chemical characterizations of two Nasicon phosphates: M.sub.0,50./sub..sup.II./sup.Ti.sub.2./sub.(PO.sub.4./sub.).sub.3./sub. (M = Mn, Co)
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SYSNO ASEP 0328515 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Hydrothermal synthesis, structural and physico-chemical characterizations of two Nasicon phosphates: M0,50IITi2(PO4)3 (M = Mn, Co) Title Hydrotermální syntéza, strukturní a fyzikálně chemická charakterizace dvou fosforečnanů typu Nasicon M0,50IITi2(PO4)3 (M = Mn, Co) Author(s) Essehli, R. (MA)
El Bali, B. (MA)
Benmokhtar, S. (MA)
Fejfarová, Karla (FZU-D)
Dušek, Michal (FZU-D) RID, ORCID, SAINumber of authors 5 Source Title Materials Research Bulletin. - : Elsevier - ISSN 0025-5408
Roč. 44, č. 7 (2009), s. 1502-15010Number of pages 9 s. Language eng - English Country GB - United Kingdom Keywords X-ray diffraction ; Jana 2006 ; Nasicon-phosphates Subject RIV BM - Solid Matter Physics ; Magnetism R&D Projects GA202/06/0757 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z10100521 - FZU-D (2005-2011) UT WOS 000266852500010 DOI 10.1016/j.materresbull.2009.02.013 Annotation Two phosphates of the family of titanium Nasicon-phosphates have been synthesized: Mn0.5IITi2(PO4)3 and Co0,5IITi2(PO4)3. Single crystal diffraction studies show that they exhibit two different structural types. The first one crystallizes in the R-3 space group, and the second one in the R-3c space group. These two compounds are clearly related to the parent Nasicon-type rhombohedral structure, which can be described using [Ti2(PO4)3] framework composed of two [TiO6] octahedral interlinked via three [PO4] tetrahedra. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2010
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