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An efficient and highly selective synthesis of (Z)-fluoroenol phosphates from hydroxy difluorophosphonates
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SYSNO ASEP 0322902 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title An efficient and highly selective synthesis of (Z)-fluoroenol phosphates from hydroxy difluorophosphonates Title Efektivní a vysoce selektivní syntéza (Z)-fluoroenol fosfátů z hydroxy difluorofosfonátů Author(s) Beier, Petr (UOCHB-X) RID, ORCID
Pohl, Radek (UOCHB-X) RID, ORCID
Alexandrova, Anastasia (UOCHB-X)Number of authors 3 Source Title Synthesis. - : Georg Thieme Verlag - ISSN 0039-7881
-, č. 6 (2009), s. 957-962Number of pages 6 s. Language eng - English Country DE - Germany Keywords phosphonates ; phosphates ; rearrangements ; eliminations ; enols Subject RIV CC - Organic Chemistry R&D Projects GP203/08/P310 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000264895300013 DOI 10.1055/s-0028-1087803 Annotation Substituted 2-aryl-2-hydroxy-1,1-difluorophosphonates undergo a reaction with potassium tert-butoxide to provide selectively (Z)-2-fluoro-1-arylvinyl phosphates in high yields. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2009
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