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Polymer ligands as donors for terbium luminescence
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SYSNO ASEP 0318540 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Polymer ligands as donors for terbium luminescence Title Polymerní ligandy jako donory pro luminiscenci terbia Author(s) Výprachtický, Drahomír (UMCH-V) RID, ORCID
Kmínek, Ivan (UMCH-V)
Pavlačková, Petra (UMCH-V) RID
Cimrová, Věra (UMCH-V) RID, ORCIDSource Title Abstract Book. - Melbourne : Varian Australia, 2008 - ISBN 978-0-9756825-5-5 Pages s. 420-421 Number of pages 2 s. Action Australasian Polymer Symposium /30./ Event date 30.11.2008-04.12.2008 VEvent location Melbourne Country AU - Australia Event type WRD Language eng - English Country AU - Australia Keywords resonance energy transfer ; terbium luminescence ; micelles Subject RIV CD - Macromolecular Chemistry R&D Projects IAA4050409 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) 1M06031 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40500505 - UMCH-V (2005-2011) Annotation Polymer ligands containing the quinolinone fluorophore and carboxyl or carboxylate binding sites were synthesized by the reaction of poly[styrene-alt-(maleic anhydride)] with 7-amino-4-methylquinolin-2(1H)-one and methanol. The ligand-to-metal energy transfer and ligand binding properties in [Tb(III)-ligand] complexes were investigated by steady-state and time-resolved luminescence spectroscopy. The emission intensity of the Tb(III) ion was greatly enhanced upon addition of the ligand. The luminescence decay curves were double-exponential with predominating longer component. Workplace Institute of Macromolecular Chemistry Contact Eva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358 Year of Publishing 2009
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