Sensors Based on Ion Transfer Voltammetry across the Polarized Ionic Liquid/Water Interface

0510125 - ÚFCH JH 2020 RIV ES eng C - Conference Paper (international conference)
Langmaier, Jan - Samec, Zdeněk
Sensors Based on Ion Transfer Voltammetry across the Polarized Ionic Liquid/Water Interface.
Proceedings of the 5th International Conference on Sensors and Electronic Instrumentation Advances. Barcelona: IFSA Publishing, 2019 - (Yurish, Y.), č. článku 026. ISBN 978-84-09-14413-6.
[Sensors and Electronic Instrumentation Advances /5./. Tenerife (ES), 25.09.2019-27.09.2019]
R&D Projects: GA ČR(CZ) GA17-05387S
Institutional support: RVO:61388955
Keywords : ion transfer voltammetry * electrochemical detection * ionic liquid
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Some electrochemical techniques such as voltammetry at the polarized interfaces between two immiscible electrolyte solutions (ITIES) represent interesting alternatives to classical electrochemistry. The benefit of the ion transfer voltammetry lies in the possibility of detection of ionic species which are not otherwise redox active. The methodology enables apart of direct determination of ionic samples (including pharmaceutical and clinical ones) also to monitor reaction processes (acidobasic, enzymatic, etc.), determination of reaction substrates and products in one experimental step, evaluation of reaction and transport kinetics, and estimation of liphilicity of involved species.
Permanent Link: http://hdl.handle.net/11104/0300670