Influence of electrode preparation on electrocatalytic activity of water soluble porphyrazine complex to hydrogen

0506998 - ÚFCH JH 2020 RIV CZ eng C - Conference Paper (international conference)
Klusáčková, Monika - Janda, Pavel - Tarábková, Hana
Influence of electrode preparation on electrocatalytic activity of water soluble porphyrazine complex to hydrogen.
Proceedings of the 11th International Students Conference Modern Analytical Chemistry. Prague: Charles University of Prague, 2015 - (Nesměrák, K.), (2015), s. 62-66. ISBN 978-80-7444-036-6.
[International Students Conference on Modern Analytical Chemistry /11./. Prague (CZ), 22.09.2015-23.09.2015]
Institutional support: RVO:61388955
Keywords : reduction * oxidation * atomic force microscopy * backscattering microscopy * cyclic voltammetry * electrocatalysis * water soluble phthalocyanine
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

The influence of electrode preparation and used electrode substrate on electrocatalytic activity of N, N`,N``,N```tetramethyl-tetra-3,4-pyridinopor-phyrazinocobalt (CoTmt-3,4-ppa) complex deposited on electrode surface for hydrogen reaction has been studied. Electrochemical deposition, spontaneous adsorption, and spin coating have been used to the modification of two different electrode substrates: annealed gold and highly oriented pyrolytic graphite. Prepared electrodes have been characterized using cyclic voltammetry, backscattering VIS spectroscopy and atomic force microscopy. The detailed comparison of surface morphology, surface coverage, surface roughness parameters, and thickness of deposited layers of CoTmt-3,4-ppa mediatoronhydrogen reaction has been investigated.
Permanent Link: http://hdl.handle.net/11104/0298539