Dust Motions in Magnetized Turbulence: Source of Chemical Complexity

0501708 - BFÚ 2019 RIV US eng J - Journal Article
Cassone, Giuseppe - Saija, F. - Šponer, Jiří - Šponer, Judit E. - Ferus, Martin - Krůs, Miroslav - Ciaravella, A. - Jimenez-Escobar, A. - Cecchi-Pestellini, C.
Dust Motions in Magnetized Turbulence: Source of Chemical Complexity.
Astrophysical Journal Letters. Roč. 866, č. 2 (2018), č. článku L23. ISSN 2041-8205. E-ISSN 2041-8213
R&D Projects: GA ČR GA17-05076S
Institutional support: RVO:68081707 ; RVO:61388955 ; RVO:61389021
Keywords : grain-grain collisions * gas-phase formation * molecule formamide * interstellar
OECD category: Astronomy (including astrophysics,space science); Astronomy (including astrophysics,space science) (UFCH-W); Astronomy (including astrophysics,space science) (UFP-V)
Impact factor: 8.374, year: 2018

In addition to the manufacture of complex organic molecules from impacting cometary and icy planet surface analogs, which is well-established, dust grain-grain collisions driven by turbulence in interstellar or circumstellar regions may represent a parallel chemical route toward the shock synthesis of prebiotically relevant species. Here we report on a study, based on the multi-scale shock-compression technique combined with ab initio molecular dynamics approaches, where the shock-wave-driven chemistry of mutually colliding isocyanic acid (HNCO) containing icy grains has been simulated by first principles. At the shock-wave velocity threshold triggering the chemical transformation of the sample (7 km s(-1)), formamide is the first synthesized species, thus being the springboard for the further complexification of the system. Also, upon increasing the shock impact velocity, formamide is formed in progressively larger amounts. More interestingly, at the highest velocity considered (10 km s(-1)), impacts drive the production of diverse carbon-carbon bonded species. In addition to glycine, the building block of alanine (i.e., ethanimine) and one of the major components of a plethora of amino acids including, e.g., asparagine, cysteine, and leucine (i.e., vinylamine), have been detected after shock compression of samples containing the most widespread molecule in the universe (H-2) and the simplest compound bearing all of the primary biogenic elements (HNCO). The present results indicate novel chemical pathways toward the chemical complexity typical of interstellar and circumstellar regions.
Permanent Link: http://hdl.handle.net/11104/0293707