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Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type
- 1.0473610 - ÚFCH JH 2018 RIV DE eng J - Journal Article
Gómez-Pozuelo, G. - Cabello, C. P. - Opanasenko, Maksym - Horáček, Michal - Čejka, Jiří
Superior Activity of Isomorphously Substituted MOFs with MIL-100(M=Al, Cr, Fe, In, Sc, V) Structure in the Prins Reaction: Impact of Metal Type.
ChemPlusChem. Roč. 82, č. 1 (2017), s. 152-159. ISSN 2192-6506. E-ISSN 2192-6506
R&D Projects: GA ČR GA14-07101S
Institutional support: RVO:61388955
Keywords : impregnated mcm-41 catalyst * organic frameworks mil-100 * solid acid catalyst
OECD category: Physical chemistry
Impact factor: 3.205, year: 2017
The catalytic behavior of isomorphously substituted MIL-100(M) (M=Al, Cr, Fe, In, Sc, V) is investigated for the synthesis of nopol through the Prins condensation ofpinene with paraformaldehyde. The large mesoporous cages of the metal-organic frameworks provide a sustainable confinement for the formation of the target product (100% selectivity for nopol over all materials studied). MIL-100(Sc) and MIL-100(V) exhibit the highest yields (up to 90%) of nopol after just 20min from the beginning of the reaction, owing to their high concentrations of accessible Lewis sites possessing intermediate acidity. The high catalytic activity (reaching almost 90%pinene conversion) even upon decreasing the amount of catalyst from 100 to 25mg (0.025 and 0.0063g(catalyst)mmol(substrate)(-1), respectively), the stability of its structure, and the possibility to use it several times, make MIL-100(V) a promising material for applications in acid-catalyzed reactions under mild reaction conditions.
Permanent Link: http://hdl.handle.net/11104/0270747
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