Structural, Redox and Spectrometric Characterization of Energetic Material FOX-7 (2,2-dinitroethene-1,1-diamine) in Solution

0459781 - ÚFCH JH 2017 RIV CZ eng C - Conference Paper (international conference)
Šimková, Ludmila - Ludvík, Jiří
Structural, Redox and Spectrometric Characterization of Energetic Material FOX-7 (2,2-dinitroethene-1,1-diamine) in Solution.
XXXVI. Moderní elektrochemické metody. Sborník přednášek. Ústí nad Labem: Best servis, 2016 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 237-241. ISBN 978-80-905221-4-5.
[Moderní elektrochemické metody /36./. Jetřichovice (CZ), 23.05.2016-27.05.2016]
R&D Projects: GA ČR GA13-21704S
Institutional support: RVO:61388955
Keywords : FOX-7 * 2,2-dinitroethene-1,1-diamine * structure
Subject RIV: CG - Electrochemistry

The investigation of energetic materials, especially organic nitro-amino-derivatives, always has attracted attention of physical chemists. However, published articles demonstrate lack of systematic study of molecules based on aliphatic backbones, rather than aromatic structures. This work represents the first systematic electrochemical and spectrometric characterization of 2,2-dinitroethene-1,1-diamine (FOX-7) in aqueous and aprotic solvent. Based on the results obtained from combination of electrochemistry with spectrometric methods, the actual structure of FOX-7 in various media was revealed, its reducibility described and radical intermediates as well as products were intercepted, isolated and characterized.
Permanent Link: http://hdl.handle.net/11104/0259944