1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes

0459722 - ÚFCH JH 2017 RIV US eng J - Journal Article
Ansari, M. A. - Mandal, A. - Paretzki, A. - Beyer, K. - Fiedler, Jan - Kaim, W.
1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes.
Inorganic Chemistry. Roč. 55, č. 11 (2016), s. 5655-5670. ISSN 0020-1669. E-ISSN 1520-510X
R&D Projects: GA MŠMT LD14129
Institutional support: RVO:61388955
Keywords : MIXED-VALENCE COMPLEXES * RUTHENIUM COMPLEXES * ELECTRON-TRANSFER
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 4.857, year: 2016

The dinuclear complexes {(μ-H2L)[Ru(bpy)2]2}(ClO4)2 ([3](ClO4)2), {(μ-H2L)[Ru(pap)2]2}(ClO4)2 ([4](ClO4)2), and the asymmetric [(bpy)2Ru(μ-H2L)Ru(pap)2](ClO4)2 ([5](ClO4)2) were synthesized via the mononuclear species [Ru(H3L)(bpy)2]ClO4 ([1]ClO4) and [Ru(H3L)(pap)2]ClO4 ([2]ClO4), where H4L is the centrosymmetric 1,5-diamino-9,10-anthraquinone, bpy is 2,2′-bipyridine, and pap is 2-phenylazopyridine. Electrochemistry of the structurally characterized [1]ClO4, [2]ClO4, [3](ClO4)2, [4](ClO4)2, and [5](ClO4)2 reveals multistep oxidation and reduction processes, which were analyzed by electron paramagnetic resonance (EPR) of paramagnetic intermediates and by UV–vis–NIR spectro-electrochemistry. With support by time-dependent density functional theory (DFT) calculations the redox processes could be assigned. Significant results include the dimetal/bridging ligand mixed spin distribution in 33+ versus largely bridge-centered spin in 43+—a result of the presence of RuII-stabilizig pap coligands. In addition to the metal/ligand alternative for electron transfer and spin location, the dinuclear systems allow for the observation of ligand/ligand and metal/metal site differentiation within the multistep redox series. DFT-supported EPR and NIR absorption spectroscopy of the latter case revealed class II mixed-valence behavior of the oxidized asymmetric system 53+ with about equal contributions from a radical bridge formulation. In comparison to the analogues with the deprotonated 1,4-diaminoanthraquinone isomer the centrosymmetric H2L2– bridge shows anodically shifted redox potentials and weaker electronic coupling between the chelate sites.
Permanent Link: http://hdl.handle.net/11104/0259888