The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts

0585187 - ÚFCH JH 2025 RIV US eng J - Journal Article
Beck, A. - Newton, Marc Adrian - van de Water, L. G. A. - van Bokhoven, J. A.
The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts.
Chemical Reviews. (2024). ISSN 0009-2665. E-ISSN 1520-6890
Institutional support: RVO:61388955
Keywords : methanol synthesis * catalysis * Cu/ZnO/Al2O3
OECD category: Physical chemistry
Impact factor: 62.1, year: 2022
Method of publishing: Limited access
https://pubs.acs.org/doi/10.1021/acs.chemrev.3c00148

The activity and durability of the Cu/ZnO/Al2O3 (CZA) catalyst formulation for methanol synthesis from CO/CO2/H2 feeds far exceed the sum of its individual components. As such, this ternary catalytic system is a prime example of synergy in catalysis, one that has been employed for the large scale commercial production of methanol since its inception in the mid 1960s with precious little alteration to its original formulation. Methanol is a key building block of the chemical industry. It is also an attractive energy storage molecule, which can also be produced from CO2 and H2 alone, making efficient use of sequestered CO2. As such, this somewhat unusual catalyst formulation has an enormous role to play in the modern chemical industry and the world of global economics, to which the correspondingly voluminous and ongoing research, which began in the 1920s, attests. Yet, despite this commercial success, and while research aimed at understanding how this formulation functions has continued throughout the decades, a comprehensive and universally agreed upon understanding of how this material achieves what it does has yet to be realized. After nigh on a century of research into CZA catalysts, the purpose of this Review is to appraise what has been achieved to date, and to show how, and how far, the field has evolved. To do so, this Review evaluates the research regarding this catalyst formulation in a chronological order and critically assesses the validity and novelty of various hypotheses and claims that have been made over the years. Ultimately, the Review attempts to derive a holistic summary of what the current body of literature tells us about the fundamental sources of the synergies at work within the CZA catalyst and, from this, suggest ways in which the field may yet be further advanced.
Permanent Link: https://hdl.handle.net/11104/0352933