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X-ray crystallography, electrochemistry, spectral and thermal analysis of some tetradentate schiff base complexes and formation constant measurements
- 1.0482872 - FZÚ 2018 RIV US eng J - Journal Article
Asadi, Z. - Savarypour, N. - Dušek, Michal - Eigner, Václav
X-ray crystallography, electrochemistry, spectral and thermal analysis of some tetradentate schiff base complexes and formation constant measurements.
Inorganic and Nano-Metal Chemistry. Roč. 47, č. 11 (2017), s. 1501-1508. ISSN 2470-1556. E-ISSN 2470-1564
R&D Projects: GA ČR(CZ) GA15-12653S
Institutional support: RVO:68378271
Keywords : X-ray crystallography * transition metal Schiff base complexes * thermogravimetry * electrochemistry * formation constant measurements
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
A series of new transition metal Schiff base complexes was synthesized via the reaction of H2L (N,N0-bis(naphthylidene)-2-aminobenzylamine) with the transition metals and characterized by elemental analysis, 1HNMR, FT-IR, UV-Vis spectroscopy, thermogravimetric analysis(TG) and in selected cases by X-ray crystallography. Thermodynamics of complex formation, electrochemistry of the metal Schiff base complexes and kinetic aspects of thermal decomposition of the complexes were also studied. Cyclic voltammogram of the complexes in acetonitrile was done to evaluate the redox behavior of the complexes.
Permanent Link: http://hdl.handle.net/11104/0283316
Number of the records: 1