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A study of the behaviour of copper in different types of silicate glasses implanted with Cu+ and O+ ions

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    0479629 - ÚJF 2018 RIV NL eng J - Journal Article
    Švecová, B. - Vařák, P. - Vytykačová, S. - Nekvindová, P. - Macková, Anna - Malinský, Petr - Bottger, R.
    A study of the behaviour of copper in different types of silicate glasses implanted with Cu+ and O+ ions.
    Nuclear Instruments & Methods in Physics Research Section B. Roč. 406, SEP (2017), s. 193-198. ISSN 0168-583X. E-ISSN 1872-9584
    R&D Projects: GA MŠMT LM2015056; GA ČR GA15-01602S
    Institutional support: RVO:61389005
    Keywords : silicate glasses * ion implantation * copper
    OECD category: Nuclear physics
    Impact factor: 1.323, year: 2017
    DOI: https://doi.org/10.1016/j.nimb.2017.03.042

    Glasses containing copper are promising photonic materials for lasing devices and all-optical components. It has already been shown that the oxidation state of the implants depends on many factors. This paper is going to report on one of them, i.e. the influence of the composition of a silicate glass matrix on the behaviour of the implanted Cu ions before and after a subsequent implantation of oxygen ions. Three types of silicate glasses having a different extent of cross-linking were implanted with copper ions with an energy of 330 keV and a fluence 1 x 10(16) ions cm(-2). Then the glasses were implanted with oxygen ions with an energy of 110 key into the same depth as the already implanted Cu ions. The concentratiori depth profiles of Cu in the glasses were studied by Rutherford Bacicscattering Spectrometry. After the implantation, the samples were characterised by optical absorption and photoluminescence spectroscopy. The samples were annealed in ambient atmosphere for 1 h at 600 degrees C, which is near the transformation temperature of those glasses. The effect of annealing on the distribution of the implants and on the absorption and emission spectra of the as-implanted glasses will be discussed as well.

    Permanent Link: http://hdl.handle.net/11104/0275603

     
     
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