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Dynamics of photogenerated polarons and polaron pairs in P3HT thin films

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    0473851 - ÚMCH 2018 RIV NL eng J - Journal Article
    Menšík, Miroslav - Pfleger, Jiří - Toman, Petr
    Dynamics of photogenerated polarons and polaron pairs in P3HT thin films.
    Chemical Physics Letters. Roč. 677, 1 June (2017), s. 87-91. ISSN 0009-2614. E-ISSN 1873-4448
    R&D Projects: GA MŠMT(CZ) LO1507
    Institutional support: RVO:61389013
    Keywords : poly(3-hexyl thiophene) * transient absorption spectroscopy * polaron and polaron pairs
    OECD category: Polymer science
    Impact factor: 1.686, year: 2017

    On the basis of the analysis of the experimental data of the transient absorption spectroscopy of thin films of regioregular poly(3-hexyl thiophene) we suggest a mechanism of the polaron pairs decay based on the coherent up and down conversion cycling between hot polaron pairs and free polarons. Compared to previously adopted models, based on single molecular processes or bimolecular collisions, the suggested model reproduced well both the polaron pairs and polaron population kinetics at short time after photoexcitation. For longer times, when the polaron pairs are already thermalized, they decay via 1-D diffusion limited bi-molecular collision processes.
    Permanent Link: http://hdl.handle.net/11104/0271211

     
     
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