High-pressure Phase Equilibrium in the {Carbon Dioxide (1) + 1-Chloropropane (2)} Binary System.

0472571 - ÚCHP 2017 RIV GB eng J - Journal Article
Chorazewski, M. - Aim, Karel - Wichterle, Ivan - Jacquemin, J. - Polishuk, I.
High-pressure Phase Equilibrium in the {Carbon Dioxide (1) + 1-Chloropropane (2)} Binary System.
Journal of Chemical Thermodynamics. Roč. 91, č. 12 (2015), s. 165-171. ISSN 0021-9614. E-ISSN 1096-3626
R&D Projects: GA AV ČR IAA400720710
Grant - others:BEMUSAC(XE) 72074-2002-04019
Institutional support: RVO:67985858
Keywords : vapour-liquid equilibrium * carbon dioxide * predictive modeling
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.196, year: 2015

The current study reports original vapour-liquid equilibrium (VLE) for the system {CO2 (1) + 1-chloropropane (2)}. The measurements have been performed over the entire pressure-composition range for the T = (303.15, 313.15 and 328.15) K isotherms. The values obtained have been used for comparison of four predictive approaches, namely the equation of state (EoS) of Peng and Robinson (PR), the Soave modification of Benedict–Webb–Rubin (SBWR) EoS, the Critical Point-based Revised Perturbed-Chain Association Fluid Theory (CP-PC-SAFT) EoS, and the Conductor-like Screening Model for Real Solvents (COSMO-RS).
Permanent Link: http://hdl.handle.net/11104/0269841