Ruthenium (II) Complexes with 6,7-Diaza[5]phenacene.

0468158 - ÚCHP 2017 CZ eng C - Conference Paper (international conference)
Beránek, Tomáš - Žádný, Jaroslav - Jakubík, Pavel - Církva, Vladimír - Storch, Jan
Ruthenium (II) Complexes with 6,7-Diaza[5]phenacene.
Book of Abstracts. 2016, s. 65. ISBN N.
[Advances in Organic, Bioorganic and Pharmaceutical Chemistry Liblice 2016 /51./. Lázně Bělohrad (CZ), 11.11.2016-13.11.2016]
R&D Projects: GA TA ČR TA01010646
Institutional support: RVO:67985858
Keywords : ruthenium cpmplexes * electronic proprties * photocatalysis
Subject RIV: CC - Organic Chemistry

In this work we focused on preparation of novel bidentate and fully aromatic N,N-ligand and its ruthenium complexes. 6,7-Diaza[5]phenacene (1) was synthetized from 4-bromoisoquinoline by microwave-assisted tandem Hyama-Heck cross coupling reaction3 followed by photocyclization (Scheme 1). With 6,7-diaza[5]phenacene (1) in our hand, we prepared some new ruthenium(II) complexes (e.g. 2) , characterized them from structural point of view and determined some of their electronic and optical properties with regard to their application potential.
Permanent Link: http://hdl.handle.net/11104/0266016