Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

0455656 - ÚACH 2016 RIV PL eng J - Journal Article
Distler, P. - Kondé, J. - John, J. - Hájková, Zuzana - Švehla, Jaroslav - Grüner, Bohumír
Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons.
Nukleonika. Roč. 60, č. 4 (2015), s. 885-891. ISSN 0029-5922. E-ISSN 1508-5791
R&D Projects: GA MŠMT(CZ) 7G13003
EU Projects: European Commission(XE) 323282 - SACSESS
Institutional support: RVO:61388980
Keywords : accelerated electrons * CyMe4-BTPhen * irradiation * radiation stability * solvent extraction
OECD category: Inorganic and nuclear chemistry
Impact factor: 0.546, year: 2015

Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone--based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.
Permanent Link: http://hdl.handle.net/11104/0256280