Optically active push-pull molecules intercalated into layered phosphates and phosphonates

0449987 - ÚMCH 2016 CZ eng A - Abstract
Zima, Vítězslav - Melánová, Klára - Svoboda, Jan - Beneš, L. - Bureš, F.
Optically active push-pull molecules intercalated into layered phosphates and phosphonates.
Workshop on Layered Materials. Praha: Ústav fyzikální chemie Jaroslava Heyrovského AV ČR,v.v.i, 2015. OP1.
[Workshop on Layered Materials. 15.09.2015-19.09.2015, Třešť]
Institutional support: RVO:61389013
Keywords : phosphate * phosphonate * optically active molecules
Subject RIV: CA - Inorganic Chemistry

We intercalated selected NLOphores, having terminal pyridine-4-yl groups, into layered hosts. Chromophores having either linear, quadrupolar or tripodal arrangement were investigated and the influence of branching and the length of the branch in the chromophore molecules on the properties of the prepared intercalates was determined. These guest compounds were intercalated into alpha modification of zirconium hydrogen phosphate, zirconium 4-sulfophenylphosphonate, and gamma modification of titanium hydrogen phosphate and the prepared intercalates were characterized by powder XRD, TGA, and IR and UV vis spectroscopy.
Permanent Link: http://hdl.handle.net/11104/0251378