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Structure and properties of hydrides of gamma-U alloys

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    0449076 - FZÚ 2016 RIV NL eng J - Journal Article
    Havela, L. - Tkach, I. - Paukov, M. - Matěj, Z. - Drozdenko, D. - Andreev, Alexander V. - Kim-Ngan, N.-T.H.
    Structure and properties of hydrides of gamma-U alloys.
    Journal of Alloys and Compounds. Roč. 645, Oct (2015), S190-S192. ISSN 0925-8388. E-ISSN 1873-4669
    Institutional support: RVO:68378271
    Keywords : uranium * hydrogen * ferromagnetism * 5f states
    Subject RIV: BM - Solid Matter Physics ; Magnetism
    Impact factor: 3.014, year: 2015

    bcc-U alloys with Mo or Zr are more resistant to hydrogen than pure U metal. High pressures of hydrogen are needed to produce hydrides. Amorphous structure of (UH3)1-xMox can be represented as the cubic structure of beta-UH3 type with grain size around 1 nm. (UH3)1-xZrx are formed in the cubic alpha-UH3 type of structure. All the hydrides are ferromagnets, with magnetic parameters (magnetic moments, Curie temperature), which can exceed those of beta-UH3 (0.9 mB/U, 165–170 K). It is deduced that alpha-UH3 has magnetic properties very similar to beta-UH3, despite rather different U–U spacing.
    Permanent Link: http://hdl.handle.net/11104/0250661

     
     
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